
This is from the Spring/Summer 2010 ad campaign and I discovered from buying the August issue of Vogue that they have continued using her as their muse for the Fall.
The ads themselves capture the heart of rustic Italy where D&G reign. They capture as well an another era when women were sexy and powerful in their dress. The fall collection was beautiful and Madonna's campaign shows it well.

A look from the collection.
Madonna has continued to be a fashion powerhouse by designing sunglasses for Dolce and Gabbana as well as designing a juniors clothing line with her daughter for Macy's. The line debuts soon the 3rd of August and is called Material Girl.